Editors: Gianturco , Franco A. When the incident electron energy is comparable to or below those of the molecular valence electrons, the physics involved is particularly rich.
Correlation and exchange effects necessary to describe such collision processes bear a close resemblance to similar efft:cts in the theory of electronic structure in molecules. Ro-vibrational excitations by low-energy electron collisions exemplify energy transfer between the electronic and nuclear motion. The role of nonadiabatic interaction is raised here.
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When the final vibrational state is in the continuum, molecular dissociation occurs. Dissociative recombination and dissociative attachment are examples of such fragmentation processes.
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The Schwinger Variational Principle: An Approach to Electron-Molecule Collisions - CaltechAUTHORS
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Dipolar dissociation dynamics in electron collisions with carbon monoxide.